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Dahotre N. B. , Ontario. 3. M. (1991) Laser Material Processing, Springer Verlag, Berlin. 4. W. 16. 5. M. (1985) Int. Rev. 85. 6. (1994) Journal of Materials Science, 29, p. 5232. 7. M. (1985) Metals and Materials 12, p. 730. 8. Kusinski J. (2000) Lasers - an Application in Materials Engineering, Akapit, Krakow. A. O. Ritchie and M. Sarikaya (Editors) 9 2003 Elsevier Ltd. All rights reserved. IN-SITU T E M OBSERVATION OF A L L O Y I N G P R O C E S S IN I S O L A T E D N A N O M E T E R - S I Z E D PARTICLES H.
In the laser chromium alloyed zones containing more carbon and chromium (characteristic for treatments when an organic binder was used for pre-deposition of powder layer on the sample surface) primarly M7C3and M23C6 carbides in the cell boundaries were present. In the alloyed zones containing more Cr and high carbon content the martensite, austenite, carbides and 8 ferrite were present in the structure. Indeed, the hardness level of these zones, rich in Cr and C, was lower than that of the zones with martensitic structure containing less Cr and high carbon content.